Preparation and Characterization of Al-Pillared Rectorite

Author:

Xu Hong Yan1,Guo Ai Hong1,Chen Xing Tong1

Affiliation:

1. Hebei United University

Abstract

. Al-pillared rectorites (Al-REC) were synthesized from natural calcium rectorite through the exchange of inter-lamellar ions with hydroxyalumina polycations. Furthermore, the morphology, composite structure and pore properties of such composite materials were investigated by Powder X-ray Diffraction (XRD), Fourier Transformation Infra-red Spectra (FTIR) and Nitrogen Adsorption-Desorption Isotherms. The products retain their layered structure and their pore structures are a slit-shaped pore between plate-like particles. The resultant products possess BJH pore volume as large as 0.04cm3g-1, high BET specific surface area of over 100m2g-1, narrow pore size distribution in the mesopore region of 7-9nm after thermal treatment at 300 °C.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference6 articles.

1. G.W. Brindley: Amer. Mineral, Vol. 41 (1956), p.91.

2. M.L. Occelli, F.E. Huggins, J.M. Dominguez, et al.: Microporous Materials, 4(1995), p.291.

3. Patricia Salerno, Sagrario Mendioroz: Applied Clay Science, Vol. 22 (2002), p.115.

4. Liu Xiyao: China Petrochemical Press, Beijing (1990).

5. J. H. de Boer, in The Structure and Properties of Porous Materials, edited by D. H. Everett and F. S. Stone, Butterworths, London, (1958).

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