α- to β Transformation on PVDF Films Obtained by Uniaxial Stretch

Author:

Sencadas Vitor1,Moreira M. Vitor1,Lanceros-Méndez Senentxu2,Pouzada António Sergio2,Gregório Filho Rinaldo3

Affiliation:

1. Universidade do Minho

2. University of Minho

3. Federal University of São Carlos

Abstract

The α to β phase transformation of PVDF through the stretching process at different temperatures was investigated. The optimum stretching conditions were studied and characterised by infrared spectroscopy and differential scanning calorimetry. The maximum β−phase content was achieved at 80°C and a stretch ratio of 5. Accompanying the phase transformation, a orientation of the polymer chains and a packing of the crystalline structure is observed. The stretch ratio does not significantly affect the degree of crystallinity.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference7 articles.

1. A.J. Lovinger, Developments in Crystalline Polymers, Vol. 1, (Ed. D.C. Basset, London, Elsevier Applied Science, 1982).

2. S. Lanceros-Mendez, J.F. Mano, A.M. Costa and V.H. Schmidt, J. Macrom. Sci. - Phys. Vol. B40 (2001), p.517.

3. S. Laceros-Mendez, M.V. Moreira, J.F. Mano, V.H. Schmidt and G. Bohannan, Ferroelectrics Vol 273 (2002), p.15.

4. A. Salimi, A. A. Yousefi, Polymer Testing 22 (2003) pp.699-704.

5. K. Matsushige, K Nagata, S. Imada and T. Takemura, Polymer (1980) Vol. 21, 1391-1397.

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