A Study of Water Influence on Carbon Monoxide Adsorption and Oxidation on Nanocrystals of: γ-Fe2O3, Au/Fe2O3 and MnxZn1-xFe2O4

Author:

Dondur V.1,Radić Nenad1,Grbić Boško1,Drofenik Miha2

Affiliation:

1. Belgrade University

2. University of Maribor

Abstract

In this paper the adsorption and oxidation of CO on nanocrystalline Au/γ-Fe2O3, Au/α- Fe2O3, γ-Fe2O3 and a series of mixed ferrite with MnxZn1-xFe2O4 composition are investigated. The catalysts were prepared by co-precipitation method and characterized using X-ray diffraction (XRPD), specific surface (BET), transition electron spectroscopy (TEM) and magnetization measurements. A temperature programmed desorption (TPD) study of the water and CO interaction with nanocrystalline adsorbents is presented. The catalytic activities towards CO oxidation increased in the following order: γ-Fe2O3 < MnxZn1-xFe2O4 < Au/γ-Fe2O3 .

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference21 articles.

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2. D.R. Schryer and G.B. Hoflund: Low-Temperature CO-Oxidation Catalysts for Long-Life CO2 Lasers, NASA Conf. Pub. 3076, Washington, (1990).

3. J.A. Aderson: J. Chem. Soc. Faraday Trans. Vol. 88 (1992), p.1201.

4. M. Haruta, S. Tsubota, T. Kobatashi, el al.: J. Catal. Vol. 144 (1993), p.175.

5. C. Cantalini, M. Faccio, G. Ferri and M. Pelino: Sens. Actuators B Vol. 19 (1994), p.437.

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