Corrosion Properties of Supersaturated Magnesium Alloy Systems

Author:

Blawert Carsten1,Heitmann V.2,Dietzel Wolfgang1,Störmer M.2,Bohne Y.2,Mändl Stephan3,Rauschenbach B.4

Affiliation:

1. GKSS-Forschungszentrum Geesthacht GmbH

2. GKSS Research Centre

3. Leibniz-Institut für Oberflächenmodifizierung

4. Universität Leipzig

Abstract

The range of applications for magnesium alloys is still limited due to their relatively poor corrosion behavior. In recent years, various new magnesium alloys were developed, some of them with improved corrosion properties, thus opening new fields of application. However, the number of alloying elements for the use in conventional cast processes is limited due to their interaction with liquid magnesium, other alloying elements or large differences in the melting temperatures. The possibilities for grain refinement by post-processing are also restricted. PVD techniques can help to produce supersaturated precipitation free and microcrystalline magnesium layers. Using ion beam and magnetron sputtering, binary or ternary Mg-Al, Mg-Ti and Mg-Sn alloy systems as well as standard alloys (AM50, AZ91 and AE42) were deposited on silicon and on magnesium substrates. The effect of the microstructure on the corrosion properties was studied by comparing as cast material and PVD coatings using potentiodynamic polarization, linear polarization resistance, and electrochemical impedance techniques.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference9 articles.

1. D.M. Seeger et al., Magnesium Technology 2005, eds. N.R. Neelameggham, H.I. Kaplan, B.R. Powell, TMS 2005, 323-328.

2. Y. Bohne et al., Surf. Coat. Technol. (doi: 10. 1016/j. surfcoat. 2005. 11. 088).

3. A. Mitsuo et al., Materials Science Forum, Vol. 419-422, 2003, 927-930.

4. T. Mitchell et al., Journal of Alloys and Compounds, 392, 2005, 127-141.

5. A. Griguceviciene et al., Journal of Electroanalytical Chemistry, 565, 2004, 203-209.

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