Study on the Thermal Sensitivity of Energetic Materials Characterized by Accelerating Rate Calorimeter (ARC)

Author:

Zhang Hong1,Zan Lu Jun2,Zhao Bo3,Qiu Hui Dong4

Affiliation:

1. Institute of Applied Physics and Chemistry Research

2. Urben Drainage Monitoring Station

3. Entry-Exit Inspection and Quarantine Burea

4. Chongqing Institute of Science and Technology

Abstract

Liquid energetic materials were not tested through traditional test methods for thermal sensitivity. Accelerating Rate Calorimeter (ARC) was scientific to test thermal sensitivity of energetic materials. The decompositions of Hexogen (RDX), Octogen (HMX), 2,4,6-Trinitrotoluene (TNT), Nitromethane (NM), Iso-propyl Nitrate (IPN) were studied by ARC. Kinetic and thermodynamics parameters were calculated and analyzed. Temperature corresponding different time to maximum rate under adiabatic condition (θ) was calculated. The results show that the thermal sensitivity of energetic materials is NM>IPN>RDX>HMX>TNT, which suggests ARC could be used in the test of thermal sensitivity of liquid energetic materials.

Publisher

Trans Tech Publications, Ltd.

Reference15 articles.

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3. Foltz M F: Thermal stability of ε-hexanitrohexaazaisowurtzitane in an estane formulation. Propellants, Explosives, Protechnics, , Vol. 19(1994), p.63.

4. WANG Peng, Du Zhi-ming: Probability distribution of thermal sensitivity of energetic materials. Chinese Journal of Energetic Materials (Hanneng Cailiao ), Vol. 15 (2007), p.633.

5. HUANG Heng-jian, LIU Xiao-bo, ZHANG zheng: Consideration of sensitivities in the analysis of explosive handing safety. Proceeding of the 8th national symposium on explosion and safety technology, Nanjing, 2004: 118-123.

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