Inquiring into Structure of Hyperbranched Polyethylene Produced in Radical Polymerization Process-Reference-Cited by-同舟云学术

Inquiring into Structure of Hyperbranched Polyethylene Produced in Radical Polymerization Process

Published:2015-04 Issue: Volume:756 Page:173-178
ISSN:1662-7482
Container-title:Applied Mechanics and Materials
language:
Short-container-title:AMM

Author:

Koval Evgeniy¹,Echevskaya Ludmila²,Matsko Mikhail³,Pestryakov Alexey³,Mayer Edward³

Affiliation:

1. Tomskneftekhim Ltd

2. Boreskov Institute of Catalysis

3. Tomsk Polytechnic University

Abstract

This paper presents the analysis of rubberlike hyperbranched polyethylene (PE) deposits in separators and high-pressure (HP) recycle system with use of NMR spectroscopy 13С, X-ray phase analysis and differential scanning calorimetry; polymer extraction separation with boiling o-xylene and comparison of fraction characteristics have been carried out. With literature data and process conditions taken into account the potential reason of such structure polymer synthesis is being under discussion.

Publisher

Trans Tech Publications, Ltd.

Link

https://www.scientific.net/AMM.756.173.pdf

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