Affiliation:
1. Boreskov Institute of Catalysis
2. UMR 7615 CNRS UPMC
Abstract
Porous ceramometal Al2O3/CoAlO/CoAl was studied by set of physicochemical techniques such as XRD, SEM, internal field59Co and27Al MAS NMR, and porosity measurements. They revealed the cermet containing three parts. First, cobalt-free large porous alumina particles which surrounded by the second oxide part representing spinel CoxAl3-xO4(x=1,2,3) oxides. And third, oxygen-free metallic part consists of cobalt metal particles covered by Co-Al oxide protecting the metallic part from oxidation. Porosity measurements ascertained high porosity (60%) and good SSA (122 m2/g). Also the enhanced adsorption of microwaves due to metallic particles randomly distributed in oxides was found.
Publisher
Trans Tech Publications, Ltd.
Reference36 articles.
1. Shelvin, S.S., Cermets ed. J.R. Tinkelpaugh and W.B. Grandall. 1966, New York: Reinold Publ. Corp.
2. Kaplan, W.D. and A. Avishai, Ceramic matrix composites (Microstructure, properties and applications), ed. I.M. Low. 2006, Cambridge, England: Woodhead Publ. Ltd.
3. Pugacheva, E.V., et al., SHS-Produced Intermetallides as Catalysts for Deep Oxidation of Carbon Monoxide and Hydrocarbons. Int. J. Self-Prop. High-Temp. Syn., 2010. 19(1): p.65.
4. Arkatova, L.A., The deposition of coke during carbon dioxide reforming of methane over intermetallides. Catalysis Today, 2010. 157(1-4): p.170.
5. Pavlova, S., et al., Monolith composite catalysts based on ceramometals for partial oxidation of hydrocarbons to synthesis gas. Natural Gas Conversion Vii, 2004. 147: p.223.
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