Recovery of Uranium (VI) from Water Solutions by Membrane Extraction

Author:

Zakrzewska Grazyna1,Bieluszka Pawel1,Chajduk Ewelina1,Wolkowicz Stanislaw2

Affiliation:

1. Institute of Nuclear Chemistry and Technology

2. National Research Institute

Abstract

The extraction of uranium from aqueous model solutions, as well as from real solutions reulting from leaching uranium ores was carried out in the system equipped with the Liqui-Cel® Extra-Flow membrane contactor with polypropylene capillary membranes. D2EHPA in toluene was used as an organic phase. Different arrangements of flow inside the membrane module were tested. The better approach appeared to be the arrangement with aqueous phase in the shell side of the contactor and organic phase inside the capillary membrane. The extraction efficiency for model solutions reached 95% and 87% for real post-leaching liquors.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference11 articles.

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2. K. Frackiewicz, K. Kiegiel, I. Herdzik-Konecko, E. Chajduk, G. Zakrzewska-Trznadel, S. Wolkowicz, Analysis of uranium supply from domestic resources, Nukleonika (2012) 58, 451−459.

3. J.A. Daoud, Zeid, M.M., Aly, H.F. Tetravalent uranium extraction by HDEHP in kerosene from phosphate medium. Solvent Extraction and Ion Exchange, 1997, Vol. 15, No. 2, pp.203-217.

4. Musikas, C., Schulz, W.W., Rydberg, J., Choppin, G.R. Principles and Practices of Solvent Extraction. New York, Marcel Dekker, 1992, pp.413-447.

5. V. K. Jain, S. G. Pillai, R. A. Pandya, Y. K. Agrawal, P. S. Shrivastav, Molecular octopus: octa functionalized calyx.

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