Physicochemical Model of Sodium Silicate Melts and Thermodynamics of Qn - Species

Author:

Koroleva Olga N.1,Tupitsyn Aleksey A.2,Bychinskyi Valeriy A.2

Affiliation:

1. UrB RAS

2. SrB RAS

Abstract

A physicochemical model of sodium silicate melts in the region from 0 to 67 mol. % Na2O is constrained. A database of sodium silicate melts is formed and coordinated with the help of high-temperature Raman spectroscopy data. The formed model shows quantitative estimation of component changes in melts vs. temperature and composition.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference32 articles.

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3. Masson C.R., Smith I.B. and Whiteway S.G. Activities and ionic distributions in liquid silicates: application of polymer theory. Canadian Journal of Chemistry. 48(9), (1970).

4. Ariskin A.A. and Barmina G.S. Simulation of Phase Equilibria at the Crystallization of Basaltic Magmas Moscow: Nauka. (2000).

5. Lacy E.D. A statistical model of polymerisation/depolymerisation relationship in silicate melts and glasses. Physics and Chemistry of Glasses. 6(5), (1965).

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