Effects of the Chemical Compositions of KF-CsF-AlF3 Middle Temperature Aluminum Flux on Melting Characteristics

Author:

Cheng Fang Jie1,Yao Jun Feng2,Wang Ying2,Yang Jun Xiang2,Zhang Guan Xing3,Long Wei Min3

Affiliation:

1. Tianjin Key Laboratory of Advanced Joining Technology

2. Tianjin University

3. State Key Laboratory of Advanced Brazing Filler Metals and Technology

Abstract

According to the KF-CsF-AlF3 ternary phase diagram, 25 samples (named group A) near the region around the E4 and E5 (ternary eutectics points), and 22 samples (named group B) near another region around the e5 (binary eutectic point) and m2 (ternary eutectics point) were prepared by the wet synthesis method. The melting curves of these samples were measured by differential scanning calorimetry (DSC). Based on the DSC data, the effects of the fluxs compositions on the melting characteristics were analyzed and summarized. The results indicated that the lowest solidus of group A samples was about 480°C, meanwhile, their liquidus was about 520~530°C, and the melting range was approximately 40°C. Furthermore, when the content of CsF was lower than 18mol%, the solidus of group A samples apparently rose to about 510°C, but the liquidus did not change greatly. The lowest solidus of group B samples was about 420°C, meanwhile, their liquidus was below 450°C, and the melting range was approximately 20~30°C. So, with this profile of melting characteristics, some of the samples of group B flux would be good substrates for aluminum alloy middle temperature brazing, with good prospects for application.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference11 articles.

1. Zhang Qiyun, Zhuang Hongshou. Brazing and Soldering Manual. Second Edition. Beijing: China Machine Press, 2008, p.45 (in Chinese).

2. Cai Zhihong, He Junsi, Yang Zhanhong, et al. Welding Technology. 2009, 38(1), 3-6(in Chinese).

3. Dai Wei, Xue Songbai, Lou Jiyuan, et al. Transactions of Nonferrous Metals Society of China. 2012, 22, 30-35.

4. Cai Zhihong, He Junsi, Yang Zhanhong, et al. Welding Equipment and Materials. 2011, 40(2): 39-42 (in Chinese).

5. Jia Hu, Qiyun Zhang. Thermochimica Acta. 2003, 404: 3-7.

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