Formation of Polymer Brushes with Diblock Copolymers on a Planar Surface

Abstract

We use molecular dynamics simulations method to investigate the behavior characteristics of AB diblock copolymers that are adsorbed on a planar surface. Adsorption density has been distinguished, depending on the adsorption manner of A-block on the (100) surface and formation of brushes. It is examined in detail that conformational behavior of the brushes affects the adsorption density. In addition, we make a comparison of linear brush with length ratio of the A-block to the chain, in the cases of the fixed length of chain and the fixed length of A-block, respectively. The result shows that the adsorption density is strongly affected by the length ratio of the A-block to the chain. And our findings can be used as a guide for fabrication and preparation of actual synthetic polymer brushes on a solid surface by the approach of physical adsorption.