Preparation of SOFC Cells by Means of Electrophoretic Deposition

Author:

Argirusis Christos1,Damjanović Tanja2,Borchardt Günter3

Affiliation:

1. Technical University Clausthal

2. SGL Technologies GmbH

3. TU Clausthal

Abstract

Solid oxide fuel cells with an electrode supported thin film electrolyte are a promising alternative to electrolyte supported single cells because of decreased electrolyte resistance. The electrophoretic deposition (EPD) of the electrolyte was performed on A-site deficient La0.75Sr0.2MnO3-δ (ULSM) from three different suspensions: (Y2O3)0.08(ZrO2)0.92 (YSZ), (Ce0.9Gd0.1)O1.955 (GDC) and La0.9Sr0.1Ga0.8Mg0.2O2.85 (LSGM) in acetylacetone and isopropanol. The thickness of the deposits was controlled by varying the conditions of the electrophoretic deposition. Because of porosity reduction in the cathode layer during sintering of the electrolytes we deposited porous cathodes (La0.8Sr0.2MnO3-δ (LSM) and La0.6Sr0.4Fe0.8Co0.2O3-δ (LSCF) ) as well as anodes (NiO/YSZ and NiO/GDC) on dense YSZ foils by applying a conductive layer on top of the surface part to be coated.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,General Materials Science

Reference15 articles.

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2. Handbook of Fuel Cells - Fundamentals, Technology and Applications, edited by W. Vielstich, A. Lamm and H.A. Gasteiger, Vol. 1-5, 2003 John Willey & Sons, Ltd. ISBN: 0471-49926-9.

3. T. Ishihara, K. Sato, Y. Mizuhara, Y. Takita: Chemistry Letters 992, (1992), p.943.

4. A. M. El-Sherik, P. Sarkar, A. Petric: Presented at the Third International Symposium on Ionic and Mixed Conducting Ceramics, ed. T. A. Ramanarayanan, Electrochemical Society Proceedings Vol. 97-24, (1998), p.643.

5. T. Ishihara, K. Sato, Y. Tacita: J. Am. Ceram. Soc. Vol. 79, (1996), p.913.

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