Lead and Cadmium Immobilization by Polymeric Sponges Coated with Hydroxyapatite

Author:

Mavropoulos Elena1,da Rocha Nilce C.C.2,Kede M.L.F.M.3,Prado da Silva Marcelo Henrique4,Moreira Josino C.3,Rossi Antonella M.5

Affiliation:

1. CBPF - Centro Brasileiro de Pesquisas Físicas

2. UFRJ

3. Fundação Oswaldo Cruz

4. Instituto Militar de Enegenharia - IME

5. Centro Brasileiro de Pesquisas Fisicas

Abstract

Polymeric sponges coated with hydroxyapatite were used in lead and cadmium uptake experiments in order to mimetizes heavy metal incorporation by bone tissue. The hydroxyapatite-coated sponges (S-HA) were obtained by hydrothermal alkali conversion from monetite. The results showed that S-HA were efficient in immobilizing Pb and Cd. The uptake experiments using hydroxyapatite powder (HA) removed almost 100% of Pb2+ and 59% of Cd2+. When polymeric sponges coated with hydroxyapatite were used, the removal of Cd2+ and Pb2+ decreased, respectively, to closely 14 % and 74%, after 24 hours sorption. Before and after sorption experiment MEV analysis indicated precipitation of pyromorphite on hydroxyapatite-coated sponges.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,General Materials Science

Cited by 2 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Polymeric sponges coated with hydroxyapatite for metal immobilization;Surface and Coatings Technology;2012-02

2. Hydroxyapatite interactions with copper complexes;Materials Science and Engineering: C;2010-08

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