Lipase-Catalysed Polymerization of Lactic Acid and the Properties of the Polymer

Abstract

Lipase-catalysed polymerization is an emerging green alternative method for the synthesis of polylactic acid (PLA) from lactic acid (LA) monomer. Use of the lipase catalyst avoids the need for potentially toxic chemical catalysts. The concentration of the lipase enzyme is one of several factors which influence the polymerization process. This paper reports on the effects of the lipase concentration on the characteristics of the low molecular weight polylactic acid (PLA) formed via lipase-catalyzed polymerization of lactic acid. The polylactic acid products made by this method are characterized by Fourier Transform Infrared Spectroscopy (FTIR). Low molecular weight polylactic acid could be successfully produced from commercial lactic acid by using the commercial lipase Lipozyme TL IM at 50 °C in a 5-hour reaction.