Hydrogen-Induced Enhancement of Atomic Diffusion in Metals

Author:

Fukai Yuh1

Affiliation:

1. The University of Tokyo

Abstract

Atomic diffusion in metals is invariably enhanced by dissolution of hydrogen, in some cases by many orders of magnitude. This is a consequence of the formation of superabundant vacancies (SAVs), one of the general properties of M-H systems. Some examples of H-induced enhancement of interdiffusion in alloys and a detailed investigation of self-diffusion in Nb hydride, NbHx, are described, together with accelerated atomic migration observed in electrodeposited metals, also a consequence of SAV formation in the electrodeposition process.

Publisher

Trans Tech Publications, Ltd.

Subject

Condensed Matter Physics,General Materials Science,Radiation

Reference17 articles.

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3. Y. Fukai, The Metal Hydrogen System, 2nd Ed., Springer, Berlin-Heidelberg, (2005).

4. H. Noh, T.B. Flanagan, B. Corundolo, and A. Craft: Scripta Metall. 25 (1991), p.225; H. Noh et al.: Scripta Metall. Vol. 26 (1992), p.353.

5. K. Watanabe, N. Ōkuma, Y. Fukai, Y. Sakamoto, and Y. Hayashi: Scripta Mater. Vol. 34 (1996), p.551.

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1. Hydrogen-Enhanced Vacancy Diffusion in Metals;The Journal of Physical Chemistry Letters;2020-07-30

2. Hydrogen-induced enhancement of atomic diffusion in electrodeposited Pd films;Journal of Alloys and Compounds;2013-12

3. Hydrogen in metallic nanomaterials;Russian Chemical Reviews;2011-09-30

4. Hydrogen-Induced Superabundant Vacancies in Metals: Implication for Electrodeposition;Defect and Diffusion Forum;2011-04

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