Diamond Coatings on Carbon Based Substrates

Author:

Haubner Roland1ORCID,Lessiak Mario1

Affiliation:

1. University of Technology Vienna

Abstract

Diamond deposition on carbon substrates is difficult, because atomic hydrogen needed for the diamond growth, attacks the graphitic and amorphous carbon of the substrate. To reduce the etching effect, the duration till diamond layer formation should be short.By controlling the diamond deposition conditions, boron addition and seeding with diamond prior to the deposition, the formation of diamond coatings is possible.Diamond coated carbon substrates are of high interest for electrochemical applications because they show electrical conductivity and are chemically inert in a wide range. Boron doped diamond shows high overvoltage for hydrogen and oxygen and allows electrochemical reactions in water without decomposing it. Diamond was deposited on glassy carbon and electro-graphite.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference29 articles.

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3. W. Kalss, Herstellung und Charakterisierung von BN und B/C/N Schichten, Doctoral Thesis, University of Technology Vienna (1998).

4. J.C. Angus, Z. Li, M. Sunkara, Y. Wang, Nucleation and Growth in the Chemical Vapor Deposition of Diamond, in 2 nd International Conference on the Applications of Diamond Films and related Materials, M. Yoshikawa, et al. (Eds. ), MY, Tokyo, Japan (1993).

5. R. Haubner, The Microstructures of Polycrystalline Diamond, Ballas and Nanocrytalline Diamond, in O. Williams (Ed. ), Nanodiamond, The Royal Society of Chemistry, Cambridge, 2014, pp.253-267.

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