Evaluation of the Sinterability of Copper-Substituted Ferrites by Means of Dilatometric Thermal Analysis

Author:

Othéro de Brito Vera Lúcia1,Cunha Stéphanie Alá1,Ribeiro Uchoas Ana Paula1,de Araújo Fabiana Faria1,Nunes Cristina Bormio2,Genova Luis Antonio3

Affiliation:

1. Instituto Tecnológico de Aeronáutica ITA

2. Universidade de São Paulo

3. Instituto de Pesquisas Energéticas e Nucleares - IPEN/CNEN

Abstract

Cobalt and cobalt-manganese spinel ferrites have magnetostrictive properties suitable for application in magneto-electric and magneto-mechanical transducers. In this work, copper-substituted ferrites of these compositions were processed by means of the ceramic method and their sinterabilities were evaluated by dilatometric thermal analyses. The results obtained suggest that copper affects the solid-state reactions for the spinel formation and lowers the required sintering temperature for the ferrites. However, the densification obtained with sintering of the copper-substituted ferrites at 950oC for 6h was only 64%, which indicates that further adjustments on the processing route must be made in order to obtain higher densities.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference12 articles.

1. I.C. Nlebedim, N. Ranvah, Y. Melikhov, P.I. Williams, J.E. Snyder, A.J. Moses and D.C. Jiles: IEEE Trans. Magn. Vol. 45 (2009).

2. S.D. Bhame and P.A. Joy: J. Phys. D: Appl. Phys. Vol. 40 (2007), p.3263.

3. A. Barba, C. Clausell, C. Felíu and M. Monzó: J. Am. Ceram. Soc. Vol. 87 (2004), p.572.

4. J. Smit and H.P. Wijn: Ferrites. (Philips' Technical Library, Eindhoven, 1959).

5. A. Goldman: Modern Ferrite Technology. (Springer 2nd ed. New York, 2006).

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