Affiliation:
1. Karamanoglu Mehmetbey University
2. Erciyes University
Abstract
Mn4+ doped and Pr3+,4+, Sm3+, Gd3+, Tb3+,4+, Ho3+, Er3+, Tm3+ and Yb3+ co-doped MgAl2Si2O8-based phosphors were prepared by conventional solid state synthesis at 1300 °C. They were characterized by thermogravimetry (TG), differential thermal analysis (DTA), X-ray powder diffraction (XRD), photoluminescence (PL) and scanning electron microscopy (SEM). The luminescence mechanism of the phosphors, which showed broad red emission bands in the range of 600-715 nm and had a different maximum intensity when activated by UV illumination, was discussed. Such a red emission can be attributed to the intrinsic 2E→4A2 transitions of Mn4+.
Publisher
Trans Tech Publications, Ltd.
Subject
Condensed Matter Physics,General Materials Science,Atomic and Molecular Physics, and Optics
Reference6 articles.
1. Y. Lin, Z. Tang, Z. Zhang, C. Nan, Luminescence of Eu2+ and Dy3+ activated R3MgSi2O8-based (R=Ca, Sr, Ba) phosphors, J. Alloys Compounds. 348 (2003) 76-79.
2. Y. Wang, Z. Wang, P Zhang, Z. Hong, X. Fan, G. Qian, Preparation of Eu2+ and Dy3+ co-activated CaAl2Si2O8-based phosphor and its optical properties, Materials Letter, 5 (2004) 3308-3311.
3. R. Łyszczek, Hydrothermal synthesis, thermal and luminescent investigations of lanthanide(III) coordination polymers based on the 4, 4'-oxybis(benzoate) ligand, J Therm Anal Calorim. 2011; doi 10. 1007/s10973-011-1987-6.
4. G. Blasse, W.L. Wanmaker, J.W. ter Vrugt, A. Bril, Philips Res. Rep. 23, (1968) 189-193.
5. T.L. Barry, Equilibria and Eu2+ Luminescence of Subsolidus Phases Bounded by Ba3MgSi2O8, Sr3MgSi2O8, and Ca3MgSi2O8, J. Electrochem. Soc. 118 (1968) 133-738.
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