Degradation of p-Toluenesulfonic Acid by Ozonation: Performance Optimization and Mechanism

Author:

Dai Qi Zhou1,Cai Shao Qing1,Hua Ming1,Wang Jia De1,Chen Jian Meng1

Affiliation:

1. Zhejiang University of Technology

Abstract

This paper explored ozonation for the treatment of pharmaceutical wastewater and p-toluenesulfonic acid (PTSA) was selected as the model pharmaceutical intermediate. The results showed that the ozonation process is efficient for the degradation of PTSA both in concentration and COD removal. The mono factor results showed that 60L/h was a suitable ozone flow rate. There were sharp difference between acid condition and alkaline condition, under acidic conditions, the direct oxidation with molecular ozone is of primary importance, and under alkaline conditions the hydroxyl oxidation starts to dominate, and pH=12 was a suitable value. Further, intermediates of PTSA degradation were analyzed and the reaction mechanism was discussed.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference10 articles.

1. Alceon Corp. Overview of available information on the toxicity of drinking water disinfectants and their by-products. Cambridge, MA. (1993).

2. Amy, G.L., M.S. Siddiqui. Ozone-bromide interactions in water treatment. Conference proceedings, AWWA Annual Conference, Philadelphia, PA. (1991).

3. Bablon, G., et al. Practical application of ozone: principles and case studies. Ozone in water treatment application and engineering. AWWARF. (1991).

4. Larin, I. K.; Spasskii, A. I.; Trofimova, E. M.; Turkin, L. E., Increase in the apparent rate constant of the reaction of hydrogen sulfide with ozone upon the treatment of the reactor surface with reaction products. Kinet Catal+, 2010, 51 (1), 1-5.

5. Baek, M. H.; Ijagbemi, C. O.; Kim, D. S., Spectroscopic studies on the oxidative decomposition of malachite green using ozone. J Environ Sci Heal A., 2010, 45 (5), 630-636.

Cited by 2 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Ozonation Catalyzed by CoxFe1 Layered Double Hydroxide for the Degradation of P-toluenesulfonic Acid;Ozone: Science & Engineering;2020-05-25

2. Emerging Pollutants;Water Environment Research;2011-01-01

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3