Affiliation:
1. Central South University, Chinese Academy of Sciences
2. Chinese Academy of Sciences
Abstract
Pitzer-Simonson-Clegg model was used to simulate the properties of the ternary system CaCl2−KCl−H2O. The Pitzer-Simonson-Clegg binary parameters and mixture parameters for the titled system at 348.15 K were obtained from the reliable experimental osmotic and solubility data. The solubility isotherms of the titled three ternary system were predicted by Pitzer-Simonson-Clegg model and compared with the available experimental data, the agreement is generally good. The solubility isotherms for the titled system CaCl2−KCl−H2O at 348. 15 K were predicted using Pitzer-Simonson-Clegg model.
Publisher
Trans Tech Publications, Ltd.
Reference10 articles.
1. W.J. Lightfoot, Equilibria in Saturated Salt Solutions. II. The Ternary Systems CaCl2-MgCl2-H2O, CaCl2-KCl-H2O and MgCl2−KCl−H2O at 75℃, J. Am. Chem. Soc. 69 (1947) 2098−2100.
2. J.M. Yang, X.L. Liu, P.P. Liang, Solubilities of Salts in the Ternary Systems NaCl + CaCl2 + H2O and KCl + CaCl2 + H2O at 75℃, Russian Journal of Physical Chemistry A. 85 (2011) 1149−1154.
3. E.A. Rashkovskaia, T.V. Mozharov, E.N. Pavlyuch, Solubility in K+, Ca2+, Ba2+, Cl-–H2O system at 75 degrees, 43 (1970) 1281–1282.
4. H.T. Ouyang, D. Zeng, H.Y. Zhou, H.J. Han, Y. Yao, Solubility of the Ternary System LiCl + NH4Cl + H2O, J. Chem. Eng. Data. 56 (2011) 1096–1104.
5. O.Y. Dong, D. Zeng, H.Y. Zhou, H.J. Han, X. Yin, Y. Du, Phase Change Materials in the Ternary System NH4Cl + CaCl2 + H2O, CALPHAD. 35 (2011) 269–275.
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2 articles.
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