Synthesis of Modifiers in the System Cao-Sio2-H2O and their Influence on the Non-Autoclave Silicate Materials’ Properties Using Aluminosilicate Binder

Abstract

Improving the hydration hardening building materials’ operational properties is possible due to the stable macro-, micro-and nanostructures’ creation by the cementing material crystalline aggregate directed modification, which can be achieved through the use of various additives acting as crystallization centers. In the course of the studies, the synthesized modifier effect nature represented by the system was revealed CaO-SiO2-H2O (CSH) on the properties of non-autoclave silicate materials using aluminosilicate binder of various compositions. It has been established that the use of an aluminosilicate binder together with the addition of a CSH modifier increases the presence of a crystalline phase at all stages of hardening, as well as intensifies the synthesis of low-basic calcium hydro silicates with a higher crystallization degree in the system CaO-SiO2(Al2O3)-H2O represented by lime and clay rocks. This contributes to the micro-reinforced crystalline framework formation of the neoplasms with increased strength. Due to this, the pore space decreases and the amount of synthesized crystalline substance increases, which helps to increase the water resistance of the samples in all compositions. The samples using an aluminosilicate binder and the addition of a CSH modifier achieve maximum strength with a CaO content of not more than 10 wt. % The optimal CSH modifier addition is up to 1.5 wt. %, with 7 wt. %, CaO content in a mixture increase in strength is up to 6%.