Electric Power Sources Based on the Seebeck Effect of Manganese Sulfides with Rare Earth Substitution

Author:

Kharkov A.M.1,Sitnikov Maxim N.1,Kretinin Vasily1,Abdelbaki Hichem2,Zelenov Fedor2,Konovalov Stepan2,Gelgorn Alexander2

Affiliation:

1. M. F. Reshetneva Aircosmic Siberian State University

2. Reshetnev Siberian State University of Science and Technology

Abstract

The thermoelectric properties of compounds with variable valence Mn1-ХReХS (0 ≤ X ≤ 0.2) in the temperature range of (80 – 1100) K are studied. The maxima on the temperature dependences of the Seebeck coefficient (thermal EMF) for all substitution concentrations and the change of the sign of the Seebeck coefficient from positive to negative with an increase in the substitution concentration in Mn1-XYbXS are determined. A model of impurity donor 4f-states is proposed and a satisfactory agreement with the data on the thermal EMF is obtained.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

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