Development of Novel Poly (ɛ-Caprolactone)/ Fluorine Substituted Hydroxyapatite Bilayer Coated 316L Ss for In Vitro Corrosion Protection

Abstract

A novel biocompatible fluorine substituted hydroxyapatite (F-HAp) / poly (ε-caprolactone) (PCL) bilayer coating on 316L SS with superior adhesion strength and admirable corrosion protection properties. PCL slurry was coated on 316L SS as a first layer using dip coating method followed by F-HAp coating as the second layer using electrodeposition method. The structural and functional group analysis of bilayer coatings were characterized by different analytical technique. Also, the mechanical properties of the bilayer coating showed higher adhesion strength than HAp and F-HAp coatings on 316L SS. The potentiodynamic polarization and electrochemical impedance spectroscopy results indicated that the admirable corrosion protection nature. The in vitro bioactivity test for coated 316L SS substrate was carried out by soaking it in the SBF solution, the induced apatite formation confirming the improved bioactivity of the specimen. Further, dissolution of metal ions was considerably reduced which was confirmed by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). The in vitro cell–material interaction of the bilayer coating was studied with human osteosarcoma MG63 cells for cell viability at 3, 7, 14 and 21 days of incubation and good biocompatibility was observed. The obtained results show that the F-HAp/PCL bilayer coating provides effective corrosion protection and enhanced bioactivity.