Thermogravimetric Study of the Oxidation Behaviour of Sintered Stainless Steels: Influence of Powder Size and Composition

Author:

Moral Cristina1,Bautista Asuncion1

Affiliation:

1. Universidad Carlos III de Madrid

Abstract

The oxidation resistance at high temperature of the sintered stainless steels highly depends on their porosity and composition. In this work, 9 different powder mixes of gas atomized (ga) and water atomized (wa) particles were prepared.waferritic AISI 434L was used as base material, mixed in different amounts (5-20% by wt.) withgaaustenitic AISI 316L orgaferritic AISI 430L. All materials were vacuum sintered at two temperatures (1175 and 1225 °C). Thermogravimetric curves of the materials at 800 °C were obtained. Logarithmic curves are used to fit the experimental mass gains of PM steels. The addition ofgapowder to thewapowder reduces the kinetic constant (k) in a remarkable way. The value ofkdepends on the amount of small pores that become blocked by the oxides when the exposure at high-temperature takes place. For similar porosity values, pure ferritic alloys show slower oxidation kinetic than duplex stainless steels.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference14 articles.

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4. S.K. Mukerherjee and G.S. Upadhayaya: Oxid. Met. Vol. 23 (1985), p.177.

5. S.O. Shah, J.R. McMillen, P.K. Samal and E. Klar: SAE Technical Paper Nº 980314, Society of Automotive Engineers, Warrendale, PA (1998).

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