Corrosion Behavior of Pb-Ca-Sn Electrodes for Copper Electrowinning

Author:

Yuan Xue Tao1,Lv Xu Dong1,Hua Zhi Qiang1,Wang Lei1,Li Tao1

Affiliation:

1. Beijing General Research Institute for Nonferrous Metals

Abstract

Anodic polarization behavior of ternary alloy Pb-0.08%Ca-1%Sn is studied by potentiodynamic polarization measurements, corrosion rate, the products on electrode surface after polarization, and microstructure of anode mud after polarization in electrowinning cell. The results show that Pb-Ca-Sn anode is easy to be passivated in electrolyte for copper electrowinning, the maintaining passivity current density is 97.72 µA•cm-2and the corrosion products on the surface of Pb-Ca-Sn electrode present loose scaly, being composed of α-PbO2, β- PbO2and PbSO4after polarization.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

Reference10 articles.

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