Author:
Gerasymchuk S. I., ,Poliuzhyn I. P.,Oliynyk L. P.,Hnativ T. B., , ,
Abstract
In the work with the help of a static method with a membrane zero-manometer, the liquid- vapor balance in the system “dimethylzinc – dimethyl telluride” in the temperature range 270– 360 K with the content of dimethylzinc as 50.00 and 70.32 % mol. The total vapor pressure was measured for both saturated and unsaturated vapors for different samples. It was found that these solutions are not azeotropic. Using the equation of state PV = nRT, according to the thermal expansion of unsaturated vapor, the average molecular weight was calculated for mixtures “dimethylzinc – dimethyltelluride” mentioned compositions. The results of this calculation indicate the absence of significant association between molecules of the solution components in the gas phase.
Publisher
Lviv Polytechnic National University
Reference15 articles.
1. Comprehensive Inorganic Chemistry II From Elements to Applications 2nd Edition - July 23, 2013. Write a review Editors-in-Chief: Jan Reedijk, Kenneth Poeppelmeier eBook. ISBN: 9780080965291.
2. Chasteen, T. G.; Bentley, R. (2003). Biomethylation of Selenium and Tellurium: Microorganisms and Plants. Chemical Reviews. 103 (1): 1-26. DOI: 10.1021/cr010210
3. Investigation of dimethyl sulfoxide electrolytes for electrodepositing thermoelectric bismuth telluride films;Nguyen;ECS Transactions,2011
4. Singh, H. B., & Sudha, N. (1996). Organotellurium precursors for metal organic chemical vapour deposition (MOCVD) of mercury cadmium telluride (MCT). Polyhedron, 15(5-6), 745-763. DOI: 10.1016/0277-5387(95)00249-x.
5. Afzaal, M., Malik, M. A., & O'Brien, P. (2007). Preparation of zinc containing materials. New Journal of Chemistry, 31 (12): 2029-2040. DOI:10.1039/b712235g.
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献