Kinetic model of photoinitiated copolymerization of monofunctional monomers till high conversions-Reference-Cited by-同舟云学术

Kinetic model of photoinitiated copolymerization of monofunctional monomers till high conversions

Published:2009-03-15 Issue:1 Volume:3 Page:1-6
ISSN:1996-4196
Container-title:Chemistry & Chemical Technology
language:
Short-container-title:ChChT

Author:

Medvedevskikh Yuriy, ,Khovanets’ Galyna,Yevchuk Iryna, ,

Abstract

Regularities of kinetics of photoinitiated copolymerization till high conversions in the systems of monofunctional methacrylate comonomers (hydroxyethyl methacrylate (HEMA), glycidyl methacrylate (GMA)) have been investigated by laser interferometry in a wide range of experimental factors (molar ratio of comonomers, photoinitiator concentration, intensity of UV-irradiation). Kinetic model of photoinitiated copolymerization of methacrylates till high conversions has been proposed on the basis of microheterogeneity conception of the polymerization process.

Publisher

Lviv Polytechnic National University

Subject

General Chemical Engineering,General Chemistry

Reference16 articles.

1. [1] Berlin А., Korolyov G., Kefeli Т. et al.: Akrylatnyje oligomery i materialy na ikh osnove. Khimiya, Moskwa 1983.

2. [2] Gryshchenko V., Maslyuk А. and Gudzera S.: Zhydkiye fotopolymernyje kompozitsiyi. Naukova Dumka, Kyiv 1985.

3. [3] Lavrov N., Syvtsov Е. and Nikolayev А.: Reaktsionnaya sreda i kinetyka polimerizatsionnykh protsessov. Syntez, Sanct-Peterburg 2001.

4. [4] Shamenkova О., Kopylova N., Semchykov Yu. et. al.: Vysokomol. Soyed. B, 2005, 47, 2045.

5. [5] Lovell L., Stansbury J., Syrpes D. et al.: Macromolecules, 1999, 32, 3913.

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Photopolymerization of Poly(Hydroxyethyl Acrylate) (PHEA): Experimental Parameters-Viscoelastic Properties Relationship;Chemistry & Chemical Technology;2023-09-20