Author:
Panchenko Tetiana, ,Evseeva Maria,Ranskiy Anatoliy,Baumer Vyacheslav,Gordienko Olga, , , , ,
Abstract
Cadmium(II) complex with salicyl aldehyde semicarbozone (Н2L) has been synthesized. Based on elemental analysis and IR spectroscopy its composition – [Cd∙Н2L∙H2O∙Cl2] – has been established. The complex crystal structure has been examined using XRD analysis. The coordination polyhedron of cadmium atom is a distorted octahedron, where two cis-positions are occupied by oxygen atoms of water molecule and carbamide fragment of H2L molecule, other positions are occupied by chlorine atoms. At the same time two edges of octahedron are combined with adjoined octahedrons and form endless zigzag chains of octahedrons in the structure along the crystallographic axis. H2L molecule is a planar one due to the presence of intramolecular hydrogen bond.
Publisher
Lviv Polytechnic National University
Subject
General Chemical Engineering,General Chemistry
Reference16 articles.
1. [1] Redayan M: Baghdad Sci. J., 2012, 9, 532.
2. [2] Mohammed H. and Al-Amery: Baghdad Sci. J., 2011, 8, 781.
3. [3] Mohammed H. and Al-Amery.: Iraq J. Sci., 2012, 53, 704.
4. [4] Sutar A., Das Y., Pattnaik S. et al.: Int. J. Mat. Sci. Appl., 2013, 8, 136.
5. Co(III), Ni(II), and Cu(II) complexes of bidentate N,O-donor Schiff base ligand derived from 4-methoxy-2-nitroaniline and salicylaldehyde