Synthesis and structure of macrocyclic dinickel(II) complex with 5-(4-pyridyl)tetrazolate as coligand-Reference-Cited by-同舟云学术

Synthesis and structure of macrocyclic dinickel(II) complex with 5-(4-pyridyl)tetrazolate as coligand

Published:2021-09-22 Issue:2 Volume: Page:3-10
ISSN:2617-3980
Container-title:Journal of the Belarusian State University. Chemistry
language:
Short-container-title:Journal of the Belarusian State University. Chemistry

Author:

Voitekhovich Sergei V.^ORCID,Kersting Berthold,Ivashkevich Oleg A.

Abstract

The dinuclear nickel(II) complex [Ni2LmClO4] + , where Lm represents a 24-membered macrocyclic hexaaza-dithiophenolate ligand, reacts with 5-(4-pyridyl)tetrazole (PyrCN4H) to give the dinuclear complex [Ni2Lm(PyrCN4)]+ . The new complex was both isolated as perchlorate or tetraphenylborate salts and characterised by elemental analysis and IR spectroscopy. The structure of [Ni2Lm(PyrCN4)]BPh4 ⋅ MeCN was determined by single crystal X-ray diffraction, showing that tetrazolate units are in a N2,N3-bridging mode to generate dioctahedral N3Ni(µ-S)2(µ-N4CPyr)NiN3 core.

Publisher

Belarusian State University

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