CO2 LASER-DRIVEN REACTIONS IN PURE ACETYLENE FLOW-Reference-Cited by-同舟云学术

CO2 LASER-DRIVEN REACTIONS IN PURE ACETYLENE FLOW

Published:2017-12-30 Issue: Volume: Page:96-101
ISSN:2500-4239
Container-title:Science Evolution
language:en
Short-container-title:

Author:

Pikhitsa Peter,Pikhitsa Peter¹,Kim Daegyu,Kim Daegyu¹,Choi Mansoo,Choi Mansoo¹

Affiliation:

1. National CRI Center for Nano Particle Control, Institute of Advanced, Machinery and Design, School of Mechanical and Aerospace Engineering, Seoul National University

Abstract

We show that multiple-photon absorption of radiation from a 10.56 μm cw CO2 laser by intermediates (ethylene, vinylidene) generated in pure acetylene flow makes them decompose to carbon dimers and excited hydrogen. The latter associates with downstream acetylene to feedback those laser absorbing intermediates thus making the reactions self-sustained in the absence of oxygen. This process is different from acetylene self-decomposition that may occur at higher temperature and pressure. The results of our work may be useful for understanding the generation of various carbon allotropes and interstellar dust from acetylene.

Publisher

Kemerovo State University

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