Characterization of fuel-induced water contamination: chemical composition, odor threshold, and ecotoxicological implications

Abstract

Fuel spills pose significant environmental risks, particularly to drinking water sources and aquatic ecosystems. The composition of fuels has changed over the decades to reduce fossil greenhouse gas emissions. In Sweden, although the number of spill incidents has declined, with around 600 cases reported annually, there remains limited knowledge on the environmental and health impacts of modern fuels. This study aimed to address this gap through comprehensive chemical analysis and ecotoxicological assessments of 31 fuel samples, including petrol, diesel, fuel oil, and marine gas oil. Using gas chromatography-mass spectrometry (GC-MS), we determined 53 substances, including aromatic and aliphatic hydrocarbons, ethers, esters, and 17 polycyclic aromatic hydrocarbons (PAHs). A key focus was on forming a stable water-accommodated fraction (WAF) to isolate non-dissolved fuel elements from water, which is crucial for assessing subsurface aquatic life and drinking water production impacts. Results indicated significant differences in fuel odor profiles, with ethers enhancing odor intensity. Petrol components showed higher water solubility than diesel, partly due to ethanol. Ecotoxicological tests revealed varying toxicity across fuels, with petrol showing the highest toxicity to aquatic organisms, although activated sludge exhibited resilience. Fuels containing water-soluble ethers posed the highest risks to drinking water, while modern diesel was of lower concern due to its low solubility and toxicity. In freshwater ecosystems, petrol and hydrophobic toxins in fuel oil had severe effects during spills. Overall, this study offers critical insights into the environmental impact of common fuels, supporting improved risk assessment and management strategies for spill mitigation and water resource protection.