A facile in-situ reaction method for preparing flexible Sb2Te3 thermoelectric thin films

Abstract

Inorganic p-type Sb2Te3 flexible thin films (f-TFs) with eco-friendly and high thermoelectric performance have attracted wide research interest and potential for commercial applications. This study employs a facile in-situ reaction method to prepare flexible Sb2Te3 thin films by rationally adjusting the synthesized temperature. The prepared thin films show good crystallinity, which enhances the electrical conductivity of ~1,440 S·cm-1 due to the weakened carrier scattering. Simultaneously, the optimized carrier concentration, through adjusting the synthesis temperature, causes the intermediate Seebeck coefficient. Consequently, a high-power factor (16.0 μW·cm-1·K-2 at 300 K) is achieved for Sb2Te3 f-TFs prepared at 623 K. Besides, the f-TFs also exhibit good flexibility due to the slight change in resistance after bending. This study specifies that the in-situ reaction method is an effective route to prepare Sb2Te3 f-TFs with high thermoelectric performance.