Affiliation:
1. Institute of Organic Chemistry, Heidelberg University, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany
Abstract
A method for accurate mass calibration covering a wide m/z range in negative-ion direct analysis in real time mass spectrometry (DART-MS) is described. It is based on a commercially available tuning solution (Agilent ES tune mix) normally applied in electrospray ionization. This acetonitrile solution is composed of ammonium trifluoroacetate, betaine, 2,4,6-tris(heptafluoropropyl)-1,3,5-triazine, and various symmetrical hexakis-(fluoroalkoxy)-phosphazenes. Upon addition of 2% (v/v) trifluoroacetic acid in negative-ion DART-MS, this mixture yields negative ions covering a range of m/z 69 to m/z 2834. Validity of the calibration procedure is demonstrated on a Fourier transform ion cyclotron resonance mass spectrometer by application to polyethylene glycol diacid and [60]fullerene. Experimental conditions and a mass reference list are provided.
Subject
Spectroscopy,Atomic and Molecular Physics, and Optics,General Medicine
Cited by
13 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献