Proton Mobility in Water Clusters-Reference-Cited by-同舟云学术

Proton Mobility in Water Clusters

Published:2012-04 Issue:2 Volume:18 Page:215-222
ISSN:1469-0667
Container-title:European Journal of Mass Spectrometry
language:en
Short-container-title:Eur J Mass Spectrom (Chichester)

Author:

Ryding Mauritz Johan¹²,Andersson Patrik Urban²³,Zatula Alexey S.¹,Uggerud Einar¹

Affiliation:

1. Mass Spectrometry Laboratory and Centre of Theoretical and Computational Chemistry, Department of Chemistry, University of Oslo, POB 1033 Blindern, NO-0315 Oslo, Norway

2. Department of Chemistry, Atmospheric Science, University of Gothenburg, SE-412 96 Göteborg, Sweden

3. AstraZeneca R&D Mölndal, Pepparedsleden 1, SE-431 83 Mölndal, Sweden

Abstract

Proton mobility in water occurs quickly according to the so-called Grotthuss mechanism. This process and its elementary reaction steps can be studied in great detail by applying suitable mass spectrometric methods to ionic water clusters. Careful choice of suitable core ions in combination with analysis of cluster size trends in hydrogen/deuterium isotope exchange rates allows for detailed insights into fascinating dynamic systems. Analysis of the experiments has been promoted by extensive and systematic quantum chemical model calculations. Detailed low-energy mechanistic pathways for efficient water rearrangement and proton transfer steps, in particular cases along short preformed “wires” of hydrogen bonds, have been identified in consistency with experimental findings.

Publisher

SAGE Publications

Subject

Spectroscopy,Atomic and Molecular Physics, and Optics,General Medicine

Link

http://journals.sagepub.com/doi/pdf/10.1255/ejms.1172

Reference48 articles.

1. Über Esterbildung

2. The Ionization and Dissociation of Water Vapor and Ammonia by Electron Impact

3. Proton Transfer, Acid-Base Catalysis, and Enzymatic Hydrolysis. Part I: ELEMENTARY PROCESSES

4. Energiebänder der tunnelnden Überschuß-Protonen in flüssigen Säuren. Eine IR-spektroskopische Untersuchung der Natur der Gruppierungen H 5 O 2 +

Cited by 13 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Surface or Internal Hydration – Does It Really Matter?;Journal of the American Society for Mass Spectrometry;2023-02-06

2. Small angle X-ray studies of short-range order in non-stoichiometric pseudoprotic ionic liquids: the influence of chemical structure;Physical Chemistry Chemical Physics;2023

3. Grotthuss Molecular Dynamics Simulations for Modeling Proton Hopping in Electrosprayed Water Droplets;Journal of Chemical Theory and Computation;2022-05-11

4. Infrared Multiple Photon Dissociation Spectroscopy Confirms Reversible Water Activation in Mn⁺(H₂O)_n, n ≤ 8;The Journal of Physical Chemistry Letters;2022-04-07

5. Getting Ready for the Hydrogen Evolution Reaction: The Infrared Spectrum of Hydrated Aluminum Hydride–Hydroxide HAlOH + (H 2 O) n −1 , n= 9–14;Angewandte Chemie International Edition;2021-06-04