Near Infrared Reflectance Spectroscopy for Online Particle Size Analysis of Powders and Ground Materials

Abstract

The cross-sensitivity of near infrared (NIR) reflectance to the particle size of powders or ground materials has long been documented but not fully exploited for particle size estimation. Diffuse reflectance of a powder sample is dependent on light scattering within its layers, and a powder's absorption and scattering coefficient are related to its particle size. This is the basis of NIR reflectance–particle size calibrations. The availability of fibre optic probes and the speed of NIR spectrometers make them suitable for remote and online sensing of particle size, in addition to providing chemical information of a powder sample. The basics of NIR reflectance spectroscopy relevant to particle size determination and its relation to sample preparations, methods of presentation, reference methods, calibration development and validation are reviewed in this paper.