Author:
Alekseev O. M.,Zabashta Yu. F.,Kovalchuk V. I.,Lazarenko M. M.,Rudnikov E. G.,Bulavin L. A.
Abstract
On the basis of experimental data obtained for the viscosity in aqueous solutions of hydroxypropyl methylcellulose (metolose), it has been found that a structural transition takes place in dilute solutions of rod-like macromolecules with the increasing temperature. Namely, macromolecules form clusters in which they are arranged in parallel to one another. It is shown that this transition is a set of local phase transitions of the first kind.
Publisher
National Academy of Sciences of Ukraine (Co. LTD Ukrinformnauka)
Subject
General Physics and Astronomy
Reference10 articles.
1. P.G. de Gennes, J. Prost. The Physics of Liquid Crystals (OxfordUniversityPress, 1993) [ISBN: 978-0-19-852024-7].
2. L. Onsager. The effects of shape on the interaction of colloidal particles. Ann. N.Y. Acad. Sci. 51, 627 (1949). Metolose/Shin-Etsu Chemical Co., Ltd (Japan) [http://www.metolose.jp/en/industrial/metolose.html].
3. O.M. Alekseev, Yu.F. Zabashta, V.I. Kovalchuk, M.M. Lazarenko, L.A. Bulavin. The structure of polymer clusters in aqueous solutions of hydroxypropylcellulose. Ukr. J. Phys. 64, 238 (2019).
4. K.M. Kovalov, O.M. Alekseev, M.M. Lazarenko, Yu.F. Zabashta, Y.E. Grabovskii, S.Y. Tkachov. Influence of water on the structure and dielectric properties of the microcrystalline and nano-cellulose. Nanoscale Res. Lett. 12, 468 (2017).
5. K. Kamide. Cellulose and Cellulose Derivatives (Elsevier Science, 2005) [ISBN: 978-0-444-82254-3].
Cited by
11 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献