Character of the interaction in the As2Te3-TISe System and Electrophysical Propertes of the Phases Obtained

Author:

ALİEV İmir,AHMEDOVA Ceyran1

Affiliation:

1. Adiyaman University

Abstract

The character of the interaction in the As2Te3-TlSe system was studied by the methods of Differential Thermal Analysis (DTA), X-ray Diffraction (XRD), Microstructure analysis (MCA), and also by measuring the microhardness and determining the density of alloys, and state diagram was constructed. It is established that the As2Te3-TlSe state diagram is a quasibinary section of the triple mutual system As, Tl // Se, Te. Two new compounds, TlAs2Te3Se and Tl3As2Se3Te3, are formed in the As2Te3-TlSe system. Both compounds are obtained in the vitreous state. Solid solutions based on As2Te3 at room temperature reach up to 3 mol.% TlSe, and based on TlSe-2 mol.% As2Te3. The electrical conductivity and thermoelectric power coefficient of the (As2Te3)1-x (TlSe)x solid solutions have been measured as functions of temperature.

Publisher

International Journal of Pure and Applied Sciences

Subject

Industrial and Manufacturing Engineering

Reference13 articles.

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2. Aliev, I.I., Aliev, O.M., Rustamov, G.P. and Ilyasov, T.M. (1988). Russ. J. Inorg, Chem, 33, 2376-2378.

3. Aliev, I.I., Babanly, M.B. and Farzaliev, A.A. (2007 May). Optical and photoelectric properties of thin glass films (As2Se3)1-x(TlSe)X (X = 0.05-0.01). XI International Conference on the Physics and Technology of Thin Films: Ivano-Frankivsk, 86.

4. Farzaliev, A.A., Aliev, I.I., Aliev, O.M. and Aliev, I.G. (2006). J. Chem. Prob., 2, 284-287.

5. Gorbachev, V.V. and Okhotin, A.S. (1972). Thermophysical properties of semiconductors. Moscow, Atomizdat, 200 p.

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