The Role of H2O2 and K2S2O8 as Oxidizing Agents for Accelerated Corrosion Testing

Abstract

In this work, the application of hydrogen peroxide (H2O2) and potassium persulfate (K2S2O8) in accelerated corrosion testing was considered. H2O2 is already used as an accelerant in the standard immersion test ASTM G110, and K2S2O8 is an oxidizing agent that shows promise for corrosion testing applications. A Koutecky-Levich approach was used to investigate the cathodic kinetics of both oxidizing agents as well as dissolved oxygen (O2). Cathodic kinetics for O2, H2O2, and S2O82− were faster when measured on a platinum electrode than when measured on an AA2060-T3 electrode. This difference was attributed to the additional limit to cathodic kinetics posed by the protective oxide film on aluminum. H2O2 was a more potent accelerant than K2S2O8 at a concentration of 0.1 M due to the faster cathodic kinetics of H2O2 on aluminum. However, K2S2O8 was more convenient to use in a laboratory setting due to its stability during storage. The severity of tests using K2S2O8 was increased by lowering the solution pH to 2.28. At the low solution pH, cathodic kinetics and extent of attack increased.