Technical Note: Syringe Cell to Avoid Crevice Corrosion on Stainless Steels During Potentiodynamic Polarization Testing

Author:

Hernández José Wilmar Calderón1,de Souza Carvalho Machado Caruline1,Costa Isolda2,de Melo Hercílio Gomes1

Affiliation:

1. Metallurgical and Materials Engineering Department, Polytechnic School, São Paulo University. Av. Professor Mello de Moraes, 2463 São Paulo, Brazil.

2. Instituto de Pesquisas Energéticas e Nucleares – IPEN/CNEN – Av. Prof. Lineu Prestes, 2242 – São Paulo, Brazil.

Abstract

In this study, an electrochemical syringe droplet cell was developed and used to evaluate the pitting corrosion resistance of Type 304 stainless steel. The cell was also adapted to perform measurements in deaerated environment, by means of continuous N2 injection. The results obtained with the syringe cells, in both conditions (aerated and deaerated), were reproducible and free of crevice corrosion because the cell configuration does not allow obtaining this condition. The proposed cell demonstrates coherency with data acquired using conventional cell arrangements, being a potential alternative to study pitting corrosion of passive metals.

Publisher

Association for Materials Protection and Performance (AMPP)

Subject

General Materials Science,General Chemical Engineering,General Chemistry

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