Early Stage of Oxidation of Mo3Si by In Situ Environmental Transmission Electron Microscopy

Author:

Gulec A.1,Yu X.X.1,Taylor M.2,Yoon A.3,Zuo J.M.3,Perepezko J.H.2,Marks L.D.1

Affiliation:

1. Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208.

2. Department of Materials Science and Engineering, University of Wisconsin-Madison, Madison, WI 53706.

3. Department of Materials Science and Engineering, University of Illinois, Urbana-Champaign, IL 61801.

Abstract

Mo-Si-based superalloys are of interest as a new family of high-temperature materials to replace Ni-based alloys. By means of in situ environmental transmission electron microscope, the transient period of the early oxidation of Mo3Si was investigated at the nanometer scale. As a result of a competition between loss of volatile MoO3 and association of SiO2 molecular units into pillars, a nanometer-sized porous SiO2 grows at a very initial stage of the oxidation of Mo3Si.

Publisher

NACE International

Subject

General Materials Science,General Chemical Engineering,General Chemistry

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