Isomerization of Limonene on Zeolite-containing Catalysts Based on Kaolin-Reference-Cited by-同舟云学术

Isomerization of Limonene on Zeolite-containing Catalysts Based on Kaolin

Published:2022-12 Issue:2 Volume:17 Page:84-93
ISSN:1857-1727
Container-title:Chemistry Journal of Moldova
language:
Short-container-title:Chem. J. Mold.

Author:

Patrylak Lyubov¹²^ORCID,Zubenko Stepan¹^ORCID,Konovalov Serhy¹^ORCID,Yakovenko Anzhela¹^ORCID,Povazhnyi Volodymyr¹^ORCID,Pertko Oleksandra¹^ORCID,Voloshyna Yulia¹^ORCID,Melnychuk Oleksandr¹^ORCID,Filonenko Mykhailo¹³^ORCID

Affiliation:

1. V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of National Academy of Sciences of Ukraine, 1, Murmanska str., Kyiv 02094, Ukraine

2. National Technical University of Ukraine “Igor Sikorskyi Kyiv Polytechnic Institute”, 37, Peremohy ave., Kyiv 03056, Ukraine

3. National Pedagogical Dragomanov University, 9, Pyrogova str., Kyiv 01601, Ukraine

Abstract

The aim of the work was to study the isomerization of limonene on zeolite-containing biporous acid catalysts based on kaolin (from Ukraine). Results of this study show that at 160°C, the maximum isomer yield was 60–65% with an 80–90% conversion. The studied samples do not have a significant accumulation of carbonaceous deposits because limonene has high solubility, which helps to remove intermediate products of transformation from the surface of the samples.

Publisher

Institute of Chemistry

Subject

Process Chemistry and Technology,Environmental Chemistry,General Chemistry

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4. Transformation of limonene into p-cymene over acid activated natural mordenite utilizing atmospheric oxygen as a green oxidant: A novel mechanism

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