Abstract
In a semi-review paper, it was discussed the notion of symmetry of polyatomic systems defined as invariance under transformations, and show that this important property of atomic matter is extremely vulnerable, and may undergo internal breakdown, subject to the presence of electronic degeneracy or pseudodegeneracy. First formulated by Landau, L. in 1934, later proved and published by Jahn and Teller, this Jahn-Teller effect (JTE) underwent tremendous developments with important applications in physics, chemistry, biology, and materials science. Less attention was paid to the roots of this phenomenon and its correct interpretation in the sense of its influence on observable properties. It is shown that electronic degeneracy and its extended form, called pseudodegeneracy, are actually the only source of spontaneous symmetry breaking (SSB) in nature, including all forms of matter, beginning with elementary particles, via nuclei, atoms, molecules, and solids. Theoretically, the vulnerability of the notion of symmetry is due to the fact that, following quantum mechanics, the separation of the motion of electrons and nuclei (and, similarly, the separation of motions of elementary particles) is approximate, and hence the classical notion of polyatomic space configuration is approximate too, with SSB as one of its main violation.
Subject
Process Chemistry and Technology,Environmental Chemistry,General Chemistry
Reference30 articles.
1. 1. Weyl, H. Symmetry. Princeton University Press: New Jesey, 1952, 176 p.
2. 2. Houtappel, R.M.F.; Van Dam, H.; Wigner, E.P. The conceptual basis and use of the geometric invariance principles. Reviews of Modern Physics, 1965, 37(4), pp. 595-632. DOI: https://doi.org/10.1103/RevModPhys.37.595
3. 3. Hargittai, I. (Ed.) Symmetry: Unifying Human Understanding. Pergamon Press: Oxford, 1989, 1058 p.
4. 4. Einstein, A. Zur elektrodynamik bewegter Korper. Annalen der Physik, 1905, 322(10), pp. 891-921. DOI: https://doi.org/10.1002/andp.19053221004;
5. 5. Einstein, A.; Lorentz, H.A.; Minkowski, H.; Weyl, H. (Eds.) The Principle of Relativity. Dover Books: New York, 1952, pp. 35-65.
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献