Abstract
Starting with the methyl 11-homodrim-8-ene-7-oxo-12-oate a two steps synthesis of methyl-11-homodrim-6,8(9)-diene-12-oate was accomplished in 87% overall yield, which on photooxygenation in the presence of tetraphenylporphyrin gave a mixture of methyl esters of 11-homodrim-7-ene-6α,9α-peroxy-12-oic and 11-homodrim-5,8-diene-7-oxo-12-oic acids 21% and 54% yields, respectively.
Publisher
Institute of Chemistry of Academy of Science of Moldova
Subject
Process Chemistry and Technology,Environmental Chemistry,General Chemistry