Author:
Ptitsyna C. O.,Ilyin A. A.,Rumyantsev R. N.,Sakharova Y. N.
Abstract
In this work we studied the effect of mechanochemical activation on the formation of the cobalt ferrite phase from iron and cobalt oxalates. X-ray phase, X-ray diffraction and synchronous thermal analysis, scanning electron microscopy, low-temperature nitrogen adsorption-desorption method were used to study the composition and properties of the resulting product. It has been established that cobalt ferrite is formed at a temperature of 1100 °C during solid-phase interaction of the initial components, and the use of mechanochemical activation of the initial components in a roller-ring vibration mill makes it possible to reduce the synthesis temperature to 400 °C. It is shown that CoFe2O4 obtained using the method of mechanochemical synthesis has a more developed specific surface area and porous structure in comparison with cobalt ferrite obtained by the ceramic method.
Publisher
Izdatel'skii dom Spektr, LLC
Reference14 articles.
1. Kaçar C., Dalkiran B., Erden P. E., Kiliç E. An amperometric hydrogen peroxide biosensor based on Co3O4 nanoparticles and multiwalled carbon nanotube modified glassy carbon electrode // J. Applied Surface Science. 2014. V. 311. P. 139 – 146. DOI: 10.1016/j.msec. 2011.10.028
2. Tourinho F. A., Franck R., Massart R. Aqueous ferrofluids based on manganese and cobalt ferrites // J. of Materials Science. 1990. V. 25, No. 7. P. 3249 – 3254.
3. Cabuil V., Dupuis V., Talbot D., Neveu S. Ionic magnetic fluid based on cobalt ferrite nanoparticles: influence of hydrothermal treatment on the nanoparticle size // J. of Magnetism and Magnetic Materials. 2011. V. 323, No. 10. P. 1238 – 1241. DOI: 10.1016/j.jmmm.2010.11.013
4. Silva J. B., Diniz C. F., Lago R. M., Mohallem N. D. Catalytic properties of nanocomposites based on cobalt ferrites dispersed in sol-gel silica // J. of Non-Crystalline Solids. 2004. V. 348. P. 201 – 204.
5. Thomas A. A., Pietro A., Emanuela M., et al. Synthesis and Characterization of Copper Ferrite Magnetic Nanoparticles by Hydrothermal Route // J. Chemical Engineering Transactions. 2016. V. 47. P. 151 – 156. DOI: 10.3303/CET1647026
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