Synthesis, XRD, EXAFS and XANES Study of Cu(II) Complexes of Aniline Dithiocarbamate

Author:

Geete Anurag1,Shrivastava B.D.2,Mishra Ashutosh3

Affiliation:

1. Department of Physics, Shri Rewa Gurjar Bal Niketan College, Sanawad, Khargone-451111, India

2. Department of Physics, Maharaja Bhoj Government P.G. College, Dhar-454001, India

3. School of Physics, Devi Ahilya University, Indore-452001, India

Abstract

In present investigation, seven copper(II) complexes were synthesized using various aniline dithiocarbamate. The synthesized Cu(II) complexes were studied for different structural and chemical parameters using XRD, EXAFS and XANES. The output obtained from X-ray studies was synthesized using Athena and Origin 6.0 software. The results of the investigation were used in determining the structures of the synthesized complexes. The particle size of the synthesized complexes ranged between 46.7 and 125.3 nm. The lattice constant of Cu(II) complexes was found 3.61-3.62 Å.

Publisher

Asian Journal of Chemistry

Subject

General Chemistry

Reference17 articles.

1. Atomic weights of the elements 2013 (IUPAC Technical Report)

2. F. William, H.J. Smith and F. Presuel-Moreno, Foundations of Materials Science and Engineering, McGraw-Hill Publishing, edn 5 (2006).

3. Metal stocks and sustainability

4. N. Krause, Modern Organocopper Chemistry, John Wiley & Sons (2002).

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