Affiliation:
1. Department of Chemistry, University of Lucknow, Lucknow-226007, India
2. Department of Chemistry, M.K.P. (P.G.) College, Dehradun-248001, India
Abstract
A series of hitherto unreported μ-oxy-bis[triphenylantimony(V)]dicarboxylates and
μ-oxy-bis[triphenylantimony(V)] chlorocarboxylates of general formula Ph3Sb(L)-O-Sb(L)Ph3 and
Ph3Sb(Cl)-O-Sb(L)Ph3, respectively have been synthesized by the metathetical reaction of
μ-oxybis-[triphenylantimony(V)]dichloride and silver salts of corresponding carboxylic acids in 1:2
and 1:1 molar ratio [where L = thiosalicyclic acid, p-nitrobenzoic acid, p-aminobenzoic acid,
p-fluorobenzoic acid, o-chlorobenzoic acid]. The newly isolated antimony carboxylates have been
identified on the basis of melting points, elemental analysis, FT-IR, 1H NMR,13C NMR, 19F NMR. The
molecular weight and conductivity data indicate the monomeric and non-electrolytic behaviour in
solution. Compounds have been evaluated for their antifungal and antibacterial activity.
Publisher
Asian Journal of Chemistry
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