Affiliation:
1. Department of Chemical Engineering, Institute of Engineering and Technology, Lucknow-226021, India
2. Department of Chemical Engineering, Indian Institute of Technology Kanpur, Kanpur-208016, India
Abstract
In present study, tri-n-butylphosphate (TBP), a classical complexing agent for metallic cations, has
been studied for the extraction of uranium into ionic liquids (ILs): 1-butyl-3-methylimidazoliumbis(
tri-fluoromethylsulfonyl)imide ([BMIM][TF2N]) and trihexyl-tetradecylphosphonium-bis(trifluoromethylsulfonyl)
imide ([P(14)666][TF2N]). Increasing HNO3 acidity of aqueous solution from 0.01
to 1 M the distribution ratio, DU decreases from 16 to 1.2 for 1.1 M TBP in [BMIM][TF2N] and the
corresponding extraction efficiency (% E) varies from ~94 to 55. In the acidic range of 1 to 8 M DU
and % E shows reversal trend of giving a local maximum at 8 M. This behaviour is compared and
validates by literature. In contrast, on increasing in aqueous acidity from 0.01 to 8 M the extraction of
uranium into [P(14)666][TF2N] ionic liquid, DU enhances from 2 to 39 and (%E) goes up from ~ 51 to 95.
Since, [P(14)666][TF2N] works better than [BMIM][TF2N] in the acidic range > 0.1. This ionic liquid
has been used for selective separation of uranium from strontium giving a DU of 63 and DSr of 2 with
98% E of uranium at 8 M acidity. To confirm the various species and groups in the formed complex,
FTIR studies have been conducted.
Publisher
Asian Journal of Chemistry