Gas Chromatographic Technique Employed for Catalytic Investigation of Novel Phthalocyanines-Reference-Cited by-同舟云学术

Gas Chromatographic Technique Employed for Catalytic Investigation of Novel Phthalocyanines

Published:2023 Issue:7 Volume:35 Page:171-1726
ISSN:0975-427X
Container-title:Asian Journal of Chemistry
language:en
Short-container-title:Asian J. Chem.

Author:

Sharanakumar T.M.¹^ORCID,Sunilkumar A.²^ORCID,Somashekar M.N.³^ORCID,Chethan B.⁴^ORCID,Kumar T. Naveen⁵^ORCID,Ravikumar C.R.⁶^ORCID

Affiliation:

1. Department of Chemistry, Ballari Institute of Technology and Management, Jnana Gangotri Campus, Bellary-583104, India

2. Department of Physics, Ballari Institute of Technology and Management, Jnana Gangotri Campus, Bellary-583104, India

3. Department of Chemistry, S.S. Margol Degree College of Arts, Science and Commerce, Shahabad Rural-585228, India

4. Department of Physics, Indian Institute of Science, Bengaluru-560012, India

5. Department of PG Chemistry, Surana College (Autonomous Institute), Bangalore-560004, India

6. Research Centre, Department of Chemistry, East-West Institute of Technology (Affiliated to Visvesvaraya Technological University) Bangalore-560091, India

Abstract

The primaquine substituted Fe(II) phthalocyanine (PQFePc) and Co(II) phthalocyanine (PQCoPc) catalysts were prepared by using amide linkage method. The physical and chemical properties have been investigated by FTIR, mass, UV-Vis, TGA, XRD and elemental analysis. The catalytic oxidation of benzyl alcohol was determined by PQFePc and PQCoPc complexes by varying parameters like temperature, oxidant/catalytic ratio and substance/catalyst ratio. The optimization of catalytic oxidation reaction has been effectively achieved for the determination of benzyl alcohol (Bzalc) to benzaldehyde (Bzald). The PQCoPc and PQFePc exhibited excellent catalytic behaviour for the oxidation of benzyl alcohol obtaining high yield and good selectivity.

Publisher

Asian Journal of Chemistry

Subject

General Chemistry

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