Synthesis, Characterization and DNA Binding Studies of N,N′-bis(2-Hydroxy-5-methylbenzylidene)- 2-hydroxy-propane-1,3-diamine Copper(II) and Nickel(II) Complexes-Reference-Cited by-同舟云学术

Synthesis, Characterization and DNA Binding Studies of N,N′-bis(2-Hydroxy-5-methylbenzylidene)- 2-hydroxy-propane-1,3-diamine Copper(II) and Nickel(II) Complexes

Published:2020 Issue:7 Volume:32 Page:1667-1675
ISSN:0975-427X
Container-title:Asian Journal of Chemistry
language:en
Short-container-title:Asian J. Chem.

Author:

Ramina ¹^ORCID,Singh Rajkumar Bhubon¹,U-wang Oinam¹^ORCID,Singh Thoudam Surchandra¹^ORCID,Jamir T. Tiakaba²^ORCID

Affiliation:

1. Department of Chemistry, Manipur University, Canchipur-795003, India

2. Department of Chemistry, Kohima Science College, Kohima-797002, India

Abstract

Two new Schiff base transition metal complexes [Cu(HL)]2.CH3CH2OH (1) and [Ni(HL)] (2) (L = N,N′-bis(2-hydroxy-5-methyl-benzylidene)-2-hydroxy-propane-1,3-diamine) were synthesized and characterized by different physico-chemical and spectroscopic techniques. Structure of complex 1 was determined by single crystal X-ray diffractometer. Both the complexes have distorted square planar geometry. The DNA binding study of two complexes was performed via electronic absorption, cyclic voltammetry, photoluminescence, and viscosity methods and found to be intercalative mode of binding.

Publisher

Asian Journal of Chemistry

Subject

General Chemistry

Reference55 articles.

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