Affiliation:
1. Department of Chemistry, Yashwantrao Mohite College of Arts, Science and Commerce, Bharati Vidyapeeth (Deemed to be University), Pune-411038, India
Abstract
Molybdenum trioxide was used as a precursor for the deposition of thin films of varied concentrations
onto the glass substrate by ultra-spray pyrolysis technique. Solutions of different concentrations viz.
0.05 M, 0.025 M, 0.0125 M were prepared and the substrate temperature varied to study the structural
properties like XRD, UV-visible spectroscopy and FESEM of the MoO3 thin films. Being transition
metal oxide molybdenum oxide (MoO3), exhibits fascinating chemical, structural, electrical and optical
properties. The samples were prepared at different temperatures of 150, 250 and 350 ºC with the spray
concentrations varying between 0.05 M, 0.025 M and 0.0125 M while the other spray operating
parameters were fixed at their optimum values. X-ray diffraction technique was used to determine the
crystalline size and nature of the films. For the substrate temperature 150 ºC, the films obtained are
amorphous in nature while the films deposited at 250 and 350 ºC were found to be crystalline in nature
giving α-MoO3 phase, which is evident from the X-ray diffraction pattern. The size of the crystal
varied from 43 to 65 nm for the prepared samples. The band-gap energy by plotting Tauc plots was
found to be in the range 2.51-3.01 eV. FESEM revealed two different types of morphological structures
viz., spherical and nanorods. The photocatalytic activity of thin films obtained was estimated from
their ability to degrade methylene blue (MB) under UV irradiation with excellent results. Antibacterial
activity of thin films was checked against Pseudomonas aeruginosa for 1, 6, 10 and 96 h.
Publisher
Asian Journal of Chemistry